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Zum Inhalt
Fakultät BCI
Projektgruppe Renewlysis

Dr. Thomas Seidensticker

Arbeitsschwerpunkt

  •     Integriertes Katalysatorrecycling für kontinuierliche Prozesse
  •     Homogene Katalyse für die Funktionalisierung von ungesättigten Oleochemikalien
  •     Flüssige Mehrphasensysteme
  •     Selektive Produktkristallisation

Lebenslauf

  • 1987  geboren in Marl (Westf.)
  • 2007-2010  Bachelor of Science, TU Dortmund Universität, “Hydroaminomethylation of methyl oleate with proline“ (Prof. Arno Behr and Dr. Andreas J. Vorholt)
  • 2010-2012  Master of Science, TU Dortmund Universität, “Nickel-catalyzed linear dimerization of isobutene” (Prof. Arno Behr)
  • 2011  Erasmus Scholarship, Forschungsaufenthalt an der University of St. Andrews mit Prof. David J. Cole-Hamilton
  • 2013-2016  Promotion in Chemie (Dr. rer. nat., mit Auszeichnung, summa cum laude), TU Dortmund Universität, “Development of Catalytic Tandem Reaction Systems in the Context of Green Chemistry” (Prof. Arno Behr and Dr. Andreas J. Vorholt)
  • 2016-2017  Post-Doc, TU Dortmund Universität, (Prof. Arno Behr)
  • seit 2017  Nachwuchsgruppenleiter, TU Dortmund Universität, Lehrstuhl für Technische Chemie
  • 2022   Hochschullehrer-Nachwuchspreis für Technische Chemie, verliehen von der DECHEMA-Fachgemeinschaft Bildung und Innovation
  • 2021   Carl-Zerbe Preis für junge Wissenschaftler, verliehen von der Deutschen Wissen­schaft­lichen Gesell­schaft für Erdöl, Erdgas und Kohle e.V. (DGMK)
  • 2021   H.P. Kaufmann-Price für die Arbeit an „Die Umsetzung ungesättigter Oleochemikalien zur Erzeugung nachhaltiger chemischer Zwischenprodukte mittels homogener Übergangsmetallkatalyse.“ verliehen von der DGF (Deutsche Gesellschaft für Fettwissenschaft).
  • 2020  Literature Preis des „Fonds der Chemischen Industrie (FCI)” (Chemical Industry Fund) für the Fachbuch "Einführung in die Chemie nachwachsender Rohstoffe” 
  • 2018  Preis für die beste Doktorarbeit auf dem Gebiet der nachhaltigen Chemie, verliehen von der Abteilung für nachhaltige Chemie der GDCh
  • 2017  Auszeichnung für die beste Dissertation im Jahr 2016 am Fachbereich Bio- und Chemieingenieurwesen der TU Dortmund
  • 2013-2015  Ph.D. Chemiefond-Stipendium des "Fonds der Chemischen Industrie (FCI)", zweijähriges Vollzeitstipendium
  • 2011-2012  “Deutschland-Stipendium”, Lanxess AG

Publikationen & Konferenzen

  • Behr, A. and Seidensticker, T. (2020) Chemistry of Renewables. Springer Nature: Berlin.
  • Behr, A. and Seidensticker, T. (2018) Einführung in die Chemie nachwachsender Rohstoffe: Vorkommen, Konversion, Verwendung. Springer Spektrum: Berlin.
  • Seidensticker, T. (2016) Development of catalytic tandem reaction systems in the context of green chemistry. Technische Universität Dortmund: München.
  • Bianga, J., Künnemann, K. U., Kampwerth, A., Gaide, T., Vorholt, A. J., Seidensticker, T., Dreimann, J. M., Vogt, D., Thermomorphic Multiphase Systems in Integrated Chemical Processes in Liquid Multiphase Systems; Kraume, M., Enders, S., Drews, A., Schomäcker, R., Engell, S., Sundmacher, K., Eds.; 2022; Vol.1, pp. 24-31.
  • Bianga, J., Künnemann, K. U., Kampwerth, A., Gaide, T., Vorholt, A. J., Seidensticker, T., Dreimann, J. M., Vogt, D., Reaction Indicators in Integrated Chemical Processes in Liquid Multiphase Systems; Kraume, M., Enders, S., Drews, A., Schomäcker, R., Engell, S., Sundmacher, K., Eds.; 2022; Vol.1, pp. 45-47.
  • Huxoll, F., Sadowski, G., Afraz, N., Petzold, M., Jokiel, M., Hecht, K., Bianga, J., Künnemann, K. U., Kampwerth, A., Gaide, T., Vorholt, A. J., Seidensticker, T., Dreimann, J. M., Vogt, D., Schlüter, S., Skiborowski, M., Thermomorphic Multiphase Systems in Integrated Chemical Processes in Liquid Multiphase Systems; Kraume, M., Enders, S., Drews, A., Schomäcker, R., Engell, S., Sundmacher, K., Eds.; 2022; Vol.1, pp. 190-236.
  • Seidensticker, T. (2017) Tandem reactions with renewables in Homogeneous Catalysis with Renewables; Behr, A., Vorholt, A. J., Eds.; pp. 107–154.
  • Behr, A.; Vorholt, A. J.; and Seidensticker, T. (2016) New trends in the catalytic functionalisation of petrochemical 1,3-dienes. In DGMK International Conference Catalysis - Novel Aspects in Petrochemistry and Refining: September 26-28, 2016, Berlin, Germany; pp. 141–152.
  • Vorholt, A. J.; Seidensticker, T.; Ostrowski, K. A.; and Behr, A. (2014) Hydroformylation - door opener to highly efficient tandem reactions to bifunctional molecules. In Preprints of the DGMK International Conference Selective Oxidation and Functionalization: Classical and Alternative Routes and Sources, October 13 - 15, 2014, Berlin, Germany: (author’s Manuscripts); Ernst, S., Ed.; pp. 47–50.

Research Papers

2024

  • Roth, T. F. H., Kühl, A., Spiekermann, M. L., Wegener, H. W., Seidensticker,T. (2024) "Biodiesel as a Sustainable Platform Chemical Enabled by Selective Partial Hydrogenation: Compounds Outplace Combustion?!",ChemSusChem, e202400036 DOI: 10.1002/cssc.202400036.

2023

  • Riemer, T. B., P. Lapac, P., Vogt, D., Seidensticker, T., (2023) "Stable and Continuous Production of Amines via Reductive Amination in a Green Switchable Solvent System with Efficient Water Removal" ACS Sustainable Chem. Eng. 11, 12959–12966, DOI: 10.1021/acssuschemeng.3c02320
  • Vondran, J., Moeschke, R., Deysenroth, T., Seidensticker, T., (2023) "Pushing Boundaries—Selective Cooling Crystallization as Tool for Selectivity Compensation and Product Purification Using a Recyclable Pd/Xantphos Catalyst in the Methoxycarbonylation of Methyl 10-Undecenoate", Eur. J. Lipid Sci. Technol., 125, 2200126. DOI: 10.1002/ejlt.202200126
  • Heider, C., Menk, M., Terhorst, M., Vogt, D., Seidensticker, T., (2023) "Synthesis of Tertiary Fatty Amines in Water: The Dual Role of Dimethylamine as Reagent and Phase Mediator in the Homogeneously Catalyzed Fatty Alcohol Amination" ACS Sustainable Chem. Eng. 11, 31, 11359–11363, DOI: 10.1021/acssuschemeng.3c02764
  • Diekamp, J., Seidensticker, T., (2023) "Synthesis Strategies towards Tagged Homogeneous Catalysts To Improve Their Separation", Angew. Chem. Int. Ed. 2023, e202304223, DOI: 10.1002/anie.202304223

  • Roth, T., Evertz, R., Kopplin, N., Tilloy, S., Monflier, E., Vogt, D., Seidensticker, T., (2023) "Continuous production of amines directly from alkenes via cyclodextrin-mediated hydroaminomethylation using only water as the solvent" Green Chem., 25, 3680-3691, DOI: 10.1039/D2GC04847G

  • Kampwerth, A., Terhorst, M., Kampling, N.,  Vogt, D., Seidensticker, T. (2023). "Synthesis of biobased amines via Pd-catalysed telomerisation of the renewable β-myrcene in a water/ethanol multiphase system: catalyst recycling enabled by a self-separating product phase". Green Chem. 25, 6345-6354, DOI: 10.1039/D3GC00453H

  • Heider, C., Winter, A., Voß, V., Vogt, D., Seidensticker, T. (2023). „Homogeneous Catalysis at its Edge: High-Temperature Ru-Catalysed Amination of Alcohols under Continuous Flow Conditions”, ChemCatChem e202201307, DOI: 10.1002/cctc.202201307

  • Metzger, J. O., Biermann, U., Seidensticker, T. (2023). „Fats and Oils as Renewable Feedstock for the Chemical Industry”, Eur. J. Lipid Sci. Technol.  , DOI: 10.1002/ejlt.202300038
  • von Vietinghoff, N., Immken, A., Seidensticker, T., de Caro, P., Thiebaud Roux, S., Agar, D. W., "Gas Introduction by Permeation into Long Fluorinated Ethylene Propylene Capillaries with Slug Flow", Chem Eng Technol 46(5), 1047-1051, DOI: 10.1002/ceat.202200557

2022

  • Vondran, J., Moeschke, R., Deysenroth, T., Seidensticker, T., (2023) "Pushing Boundaries—Selective Cooling Crystallization as Tool for Selectivity Compensation and Product Purification Using a Recyclable Pd/Xantphos Catalyst in the Methoxycarbonylation of Methyl 10-Undecenoate" Eur. J. Lipid Sci. Technol., DOI: 10.1002/ejlt.202200126

  • Hares, K., Vogelsang, D., Wernsdörfer, C.S., Panke, D., Vogt, D., Seidensticker, T. (2022). „Palladium-catalyzed synthesis of mixed anhydrides via carbonylative telomerization” Catal. Sci. Technol., 12, 3992-4000, DOI: 10.1039/D2CY00486K .

  • Vondran, J., Benninghoff, T., Emminghaus, A.I., Seidensticker, T., (2022). "Catalytic Synthesis of Methyl 9,10-dihydroxystearate from Technical Feedstocks in Continuous Flow via Epoxidation and Hydrolysis". Eur. J. Lipid Sci. Technol. 124(7), DOI: 10.1002/ejlt.202200041 .
  • Huxoll, F. , Kampwerth, A. , Seidensticker, T. , Vogt, D. , Sadowski, G. (2022). "Predicting Solvent Effects on Homogeneity and Kinetics of the Hydroaminomethylation: A Thermodynamic Approach Using PC-SAFT". Ind. Eng. Chem. Res. 61, 5, 2323–2332, DOI: 10.1021/acs.iecr.1c03891 .
  • Vondran, J., Seifert, A.I., Schäfer, K., Laudanski, A., Deysen, T., Wohlgemuth, K., Seidensticker, T., (2022). "Progressing the Crystal Way to Sustainability: Strategy for Developing an Integrated Recycling Process of Homogeneous Catalysts by Selective Product Crystallization". Ind. Eng. Chem. Res. 61(27), 9621–9631, DOI: 10.1021/acs.iecr.2c00476 .
  • Heider, C., Pietschmann, D., Vogt, D., Seidensticker, T. (2022). „Selective Synthesis of Primary Amines by Kinetic-based Optimization of the Ruthenium-Xantphos Catalysed Amination of Alcohols with Ammonia”, ChemCatChem e202200788, DOI: 10.1002/cctc.202200788 .
  • Vondran, J., Peters, M., Schnettger, A,. Sichelschmidt, C., Seidensticker, T., (2022). "From tandem to catalysis – organic solvent nanofiltration for catalyst separation in the homogeneously W-catalyzed oxidative cleavage of renewable methyl 9,10-dihydroxystearate". Catal. Sci. Technol., DOI: 10.1039/D1CY02317A .

2021

  • Vondran, J., Peters, M., Schnettger, A,. Sichelschmidt, C., Seidensticker, T., (2022). "From tandem to catalysis – organic solvent nanofiltration for catalyst separation in the homogeneously W-catalyzed oxidative cleavage of renewable methyl 9,10-dihydroxystearate". Catal. Sci. Technol., DOI: 10.1039/D1CY02317A.
  • Gladius, A. W., Vondran, J., Ramesh, Y., Seidensticker, T., Agar, D. V. (2021). "Slug flow as tool for selectivity control in the homogeneously catalysed solvent-free epoxidation of methyl oleate". J. Flow Chem. 11, 407-427, DOI: 10.1007/s41981-021-00199-6.
  • Vondran, J., Pela, J., Palczewski, D., Skiborowski, M., Seidensticker, T. (2021). "Curse and Blessing–The Role of Water in the Homogeneously Ru-Catalyzed Epoxidation of Technical Grade Methyl Oleate". ACS Sustainable Chem. Eng. 9 (34), 11469–11478, DOI: 10.1021/acssuschemeng.1c03573.
  • Künnemann, K. U., Weber, D., Becquet, C., Tilloy, S., Monflier, E., Seidensticker, T., Vogt, D. (2021). "Aqueous Biphasic Hydroaminomethylation Enabled by Methylated Cyclodextrins: Sensitivity Analysis for Transfer into a Continuous Process", ACS Sustainable Chem. Eng.9, 273–283, DOI: 10.1021/acssuschemeng.0c07125.
  • Huxoll, F., Jameel, F., Bianga, J., Seidensticker, T., Stein, M., Sadowski, G., Vogt, D. (2021) "Solvent Selection in Homogeneous Catalysis—Optimization of Kinetics and Reaction Performance", ACS Catal., 11, 590–594, DOI: 10.1021/acscatal.0c04431.

2020

  • Terhorst, M., Kampwerth, A., Marschand, A., Vogt, D., Vorholt, A. J., Seidensticker, T. (2020). "Facile catalyst recycling by thermomorphic behaviour avoiding organic solvents: a reactive ionic liquid in the homogeneous Pd-catalysed telomerisation of the renewable β-myrcene", Catal. Sci. Technol. 10, 1827–1834, DOI: 10.1039/C9CY02569C.
  • Terhorst, M., Heider, C., Vorholt, A., Vogt, D., Seidensticker, T. (2020). "Productivity Leap in the Homogeneous Ruthenium-Catalyzed Alcohol Amination through Catalyst Recycling Avoiding Volatile Organic Solvents", ACS Sustainable Chem. Eng. 8, 9962–9967, DOI: 10.1021/acssuschemeng.0c03413.
  • Künnemann, K. U., Bianga, J., Scheel, R., Seidensticker, T., Dreimann, J. M., Vogt, D. (2020). "Process Development for the Rhodium-Catalyzed Reductive Amination in a Thermomorphic Multiphase System", Org. Process Res. Dev. 24, 41–49, DOI: 10.1021/acs.oprd.9b00409.
  • Künnemann,K. U., Schurm, L., Lange, D., Seidensticker, T., Tilloy, S., Monflier, E., Vogt, D., Dreimann, J. M. (2020). "Continuous hydroformylation of 1-decene in an aqueous biphasic system enabled by methylated cyclodextrins", Green Chem. 22, 3809–3819, DOI: 10.1039/D0GC00820F.
  • Herrmann, N., Köhnke, K., Seidensticker, T. (2020). "Selective Product Crystallization for Concurrent Product Separation and Catalyst Recycling in the Isomerizing Methoxycarbonylation of Methyl Oleate", ACS Sustainable Chem. Eng. 8, 10633–10638, DOI: 10.1021/acssuschemeng.0c03432
  • Herrmann, N., Bianga, M. Palten, J., Riemer, T., Vogt, D., Dreimann, J. M., Seidensticker, T. (2020). "Improving Aqueous Biphasic Hydroformylation of Unsaturated Oleochemicals Using a Jet‐Loop‐Reactor", Eur. J. Lipid Sci. Technol. 122, 1900166 p. 1-8, DOI: 10.1002/ejlt.201900166
  • Bianga, J., Künnemann, K. U., Goclik, L., Schurm, L., Vogt, D., Seidensticker, T. (2020). "Tandem Catalytic Amine Synthesis from Alkenes in Continuous Flow Enabled by Integrated Catalyst Recycling", ACS Catal. 10, 6463–6472, DOI: 10.1021/acscatal.0c01465
  • Bianga, J., Kopplin, N., Hülsmann, J., Vogt, D., Seidensticker, T. (2020). "Rhodium‐Catalysed Reductive Amination for the Synthesis of Tertiary Amines", Adv. Synth. Catal. 362, 4415-4424, DOI: 10.1002/adsc.202000746
  • Bianga,J., Herrmann, N., Schurm, L., Gaide, T., Dreimann, J. M., Vogt, D., Seidensticker, T. (2020). "Improvement of Productivity for Aqueous Biphasic Hydroformylation of Methyl 10‐Undecenoate: A Detailed Phase Investigation", Eur. J. Lipid Sci. Technol. 122, 1900317 p. 1-7, DOI: 10.1002/ejlt.201900317

2019

  • Herrmann, N., Bianga, J., Gaide, T., Drewing, M., Vogt, D., Seidensticker, T. (2019). "Aqueous biphasic hydroformylation of methyl oleate: a green solvent-only strategy for homogeneous catalyst recycling", Green Chem. 21, 6738–6745, DOI: 10.1039/C9GC02868D

2018

  • Vogelsang, D., Dittmar, M., Seidensticker, T., Vorholt, A. J. (2018). "Palladium-catalysed carboxytelomerisation of β-myrcene to highly branched C 21 -esters", Catal. Sci. Technol.8, 4332–4337, DOI: 10.1039/C8CY00769A
  • Peters, M., Vogelsang, D., Seidensticker, T., Vogt, D., Dreimann, J. M. (2018). "Prozessintensivierung via organophiler Nanofiltration - Entwicklungen in der Rückgewinnung homogener Übergangsmetallkatalysatoren", Chem. Ing. Tech. 90, 1177, DOI: 10.1002/cite.201855101

2017

  • Furst, M. R. L., Korkmaz, V., Gaide, T., Seidensticker, T., Behr, A., Vorholt, A. J. (2017). "Tandem Reductive Hydroformylation of Castor Oil Derived Substrates and Catalyst Recycling by Selective Product Crystallization", ChemCatChem 9, 4319–4323, DOI: 10.1002/cctc.201700965

2016

  • Seidensticker, T., Vosberg, J. M., Ostrowski, K. A., Vorholt, A. J. (2016). "Rhodium-Catalyzed Bis- Hydroaminomethylation of Linear Aliphatic Alkenes with Piperazine", Adv. Synth. Catal. 358, 610–621, DOI: 10.1002/adsc.201500896
  • Seidensticker, T., Möller, D., Vorholt, A. J. (2016). "Merger of Johnson–Claisen rearrangement and alkoxycarbonylation for atom efficient diester synthesis", Tetrahedron Lett. 57, 371–374, DOI: 10.1016/j.tetlet.2015.12.032
  • Seidensticker, T., Busch, H., Diederichs, C., von Dincklage, J. J., Vorholt, A. J. (2016). "From Oleo Chemicals to Polymer: Bis -hydroaminomethylation as a Tool for the Preparation of a Synthetic Polymer from Renewables", ChemCatChem 8, 2890–2893, DOI: 10.1002/cctc.201600629
  • Ostrowski, K. A., Vogelsang, D., Seidensticker, T., Vorholt, A. J. (2016). "Direct Synthesis of an α,ω-Diester from 2,7-Octadienol as Bulk Feedstock in Three Tandem Catalytic Steps", Chem. Eur. J. 22, 1840–1846, DOI: 10.1002/chem.201503785
  • Kämper, A., Kucmierczyk, P., Seidensticker, T., Vorholt, A. J., Franke, R., Behr, A. (2016). "Ruthenium-catalyzed hydroformylation: from laboratory to continuous miniplant scale", Catal. Sci. Technol. 6, 8072–8079, DOI: 10.1039/C6CY01374K

2015

  • Seidensticker, T., Furst, M. R. L., Frauenlob, R., Vondran, J., Paetzold, E., Kragl, U., Vorholt, A. J. (2015). "Palladium-Catalyzed Aminocarbonylation of Aliphatic Alkenes with N,N -Dimethylformamide as an In Situ Source of CO", ChemCatChem 7, 4085–4090, DOI: 10.1002/cctc.201500824

2014

  • Jiménez-Rodriguez,C., Núñez-Magro, A. A., Seidensticker, T., Eastham, G. R., Furst, M. R. L., Cole-Hamilton, D. J. (2014). "Selective formation of α,ω-ester amides from the aminocarbonylation of castor oil derived methyl 10-undecenoate and other unsaturated substrates", Catal. Sci. Technol. 4, 2332–2339, DOI: 10.1039/C4CY00158C
  • Behr, A., Seidensticker, T., Vorholt, A. J. (2014). "Diester Monomers from Methyl Oleate and Proline via Tandem Hydroaminomethylation-Esterification Sequence with Homogeneous Catalyst Recycling using TMS-Technique", Eur. J. Lipid Sci. Technol. 116, 477–485, DOI: 10.1002/ejlt.201300224
  • Behr, A., Rentmeister, N., Seidensticker, T., Vosberg, J., Peitz, S., Maschmeyer, D. (2014). "Highly Selective Dimerization and Trimerization of Isobutene to Linearly Linked Products by Using Nickel Catalysts", Chem. Asian J. 9, 596–601, DOI: 10.1002/asia.201301263
  • Behr, A., Rentmeister, N., Seidensticker, T., Faßbach, T. A., Peitz, S., Maschmeyer, D. (2014). "Nickel catalyzed dimerization reactions of vinylidene compounds: Head-to-head couplings and catalyst stabilization", J. Mol. Catal. A: Chem. 395, 355–363, DOI: 10.1016/j.molcata.2014.08.043

2013

  • Furst,M. R. L., Seidensticker, T., Cole-Hamilton, D. J. (2013). "Polymerisable di- and triesters from Tall Oil Fatty Acids and related compounds", Green Chem. 15, 1218–1225, DOI: 10.1039/C3GC37071B

Review Articles

2021

  • Vondran,J., Furst, M. R. L., Eastham, G., Seidensticker, T., Cole-Hamilton, D. J. (2021). „The Magic of Alpha: The chemistry of a remarkable bidentate phosphine, 1,2-bis(di-tert-butylphosphinomethyl)benzene”, Chem. Rev. 121 (11), 6610–6653, DOI: 10.1021/acs.chemrev.0c01254

2019

  • Bianga, J., Künnemann, K. U., Gaide, T., Vorholt, A. J., Seidensticker, T., Dreimann, J. M., Vogt, D. (2019). "Thermomorphic Multiphase Systems - Switchable Solvent Mixtures for the Recovery of Homogeneous Catalysts in Batch and Flow Processes", Chem. Eur. J. 25, 11586–11608, DOI: 10.1002/chem.201902154

2018

  • Herrmann, N., Vogelsang, D., Behr, A., Seidensticker, T. (2018). "Homogeneously Catalyzed 1,3‐Diene Functionalization – A Success Story from Laboratory to Miniplant Scale", ChemCatChem 10, 5342–5365, DOI: 10.1002/cctc.201801362

2017

  • Dreimann,J. M., Faßbach, T. A., Fuchs, S., Fürst, M. R. L., Gaide, T., Kuhlmann, R., Ostrowski, K. A., Stadler, A., Seidensticker, T., Vogelsang, D., Warmeling, H. W. F., Vorholt, A. J. (2017). "Vom Laborkuriosum zum kontinuierlichen Prozess. Die Entwicklung thermomorpher Lösungsmittelsysteme", Chem. Ing. Tech. 89, 252–262, DOI: 10.1002/cite.201600119

2016

  • Seidensticker, T., Vorholt, A. J., Behr, A. (2016). "The mission of addition and fission - catalytic functionalization of oleochemicals", Eur. J. Lipid Sci. Technol. 118, 3–25, DOI: 10.1002/ejlt.201500190
  • Seidensticker,T., Engel, R. V., Pogrzeba, T. (2016). "Weimar 2016: Catalysis Strikes Back", ChemCatChem 8, 1987–1989, DOI: 10.1002/cctc.201600506

2015

  • Behr, A., Vorholt, A. J., Seidensticker, T. (2015). "An Old Friend in a New Guise-Recent Trends in Homogeneous Transition Metal Catalysis", Chem. Bio. Eng. 2, 6–21, DOI: 10.1002/cben.201400034

2014

  • Behr, A., Vorholt, A. J., Ostrowski, K. A., Seidensticker, T. (2014). "Towards resource efficient chemistry: tandem reactions with renewables", Green Chem. 16, 982–1006, DOI: 10.1039/C3GC41960F