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Primary amines from alkenes and carbonyl compounds: highly selective hydrogenation of oximes using a homogeneous Ru-catalyst
The efficient production of aliphatic primary amines is still a major challenge despite their production on a large scale. Particularly when consideri
Nickel(BiPhePhos)-Catalyzed Hydrocyanation of Styrene—Highly Increased Catalytic Activity by Optimized Operational Procedures
Nitriles are versatile and highly desired chemical intermediates for a range of products. Their economic large-scale production requires highly effici
Biodiesel as a Sustainable Platform Chemical Enabled by Selective Partial Hydrogenation: Compounds Outplace Combustion?!
Natural plant oil derivatives such as biodiesels hold a big share of polyunsaturated components, which cause tremendous selectivity and activity issue
Polymer-Grade Bio-Monomers from Oleochemicals by Combining Homogeneous Catalysis and Selective Product Crystallization in an Integrated Process
The homogeneously catalyzed methoxycarbonylation of bio-based methyl 10-undecenoate (C11-DME) produces linear 1,12-dimethyl dodecanedioate…
Stable and Continuous Production of Amines via Reductive Amination in a Green Switchable Solvent System with Efficient Water Removal
We present highly selective Rh-catalyzed reductive amination (RA) with integrated recycling of the homogeneous catalyst via a thermomorphic multiphase…
Synthesis of Tertiary Fatty Amines in Water: The Dual Role of Dimethylamine as Reagent and Phase Mediator in the Homogeneously Catalyzed Fatty Alcohol Amination
The amination of long-chain fatty alcohols with dimethylamine to the desired tertiary amines proceeds in water as the solvent with unprecedented…
Homogeneous Catalysis at its Edge: High-Temperature Ru-Catalysed Amination of Alcohols under Continuous Flow Conditions
A homogeneous ruthenium-based alcohol amination at unique conditions is presented: Continuous flow conditions allowed very high temperatures to be rea
Selective Synthesis of Primary Amines by Kinetic-based Optimization of the Ruthenium-Xantphos Catalysed Amination of Alcohols with Ammonia
A highly selective and reliable protocol for the synthesis of primary amines directly from ammonia and alcohols using a robust and commercially...
Norman Hermann completes his doctorate
Smiling like a winner. You did it! Congratulations Norman!
